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Radical addition reactions on 1,1-difluoro-1-olefins

โœ Scribed by Minoru Suda

Book ID
104235216
Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
92 KB
Volume
22
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Radical addition reactions on l,l-difluoro-1-olefins produced adducts having attacking radical species on the terminal carbon. 'H-NMR(CDC13) 0.88(3H), 0.95(3H), 1.2-2.0(228), 2.62(2H); "F-NMR (CDC13) -28_4(t,J=17Hz); correct elemental analysis.

๐Ÿ“œ SIMILAR VOLUMES

Free radical addition of 1,3,5 - trioxan
Free radical addition of 1,3,5 - trioxan to olefins
โœ I. Rosenthal ๐Ÿ“‚ Article ๐Ÿ“… 1968 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 78 KB

In a recent publication (1) we have reported the light-induced addition of acetals to olefins which led to the corresponding monoalkyl acetal derivatives. We report now the peroxide-induced addition of 1.3,5-trioxan to olefins at elevated temperatures.