Radical Addition of Dimethyl 2-Ethynylcyclopropane-1,1-dicarboxylate to Electron-Rich Olefins.
β Scribed by Jeffrey H. Byers; Peter H. Goff; Nicholas J. Janson; Michael G. Mazzotta; John E. Swigor
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 19 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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The circular dichrokm and electronic spectra of the 2,2'dimethyl-l,l'-binaphthyl anion radical have been studied. The assimments of the complicated absorption bands of :hespecies were made with theaid of the s&s in the circular dichroism spectrum and the dihedral angle of the anion radical was set i
## Abstract In the presence of 1,1^β²^βazobis(cyclohexanecarbonitrile) (ACHCN), the reaction of bis(naphthβ1,8βdiylβ8βoxy)hydrophosphorane with an equimolar amount of terminal and internal olefins gave the corresponding alkylphosphoranes. In the reactions with styrene and methyl acrylate, 2:1 olefin