Radical addition of polychloromethanes toα,α-dichlorovinyl compounds
✍ Scribed by N. V. Kruglova; Sh. A. Karapet'yan; R. Kh. Freidlina
- Book ID
- 118288910
- Publisher
- Springer
- Year
- 1975
- Tongue
- English
- Weight
- 411 KB
- Volume
- 24
- Category
- Article
- ISSN
- 1573-9171
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract α‐(Phenyltelluro)esters **2** reacted with electron‐rich alkenes **3** in the presence of a catalytic amount of azobisisobutyronitrile (AIBN) as an initiator to give the corresponding addition products **4**. This carbotelluration of alkenes proceeded via a radical chain mechanism invol
Enantioselective conjugate addition reactions of alkyl radicals to a 0 -phenylsulfonyl enones are described. A bis-oxazoline-zinc triflate complex proved to be an effective catalyst leading to high enantioselectivities and chemical yields.