Radical addition of alkylbenzenes to α,α-dichlorovinyl compounds
✍ Scribed by R. Kh. Freidlina; N. V. Kruglova; M. Ya. Khorlina
- Book ID
- 112437273
- Publisher
- Springer
- Year
- 1976
- Tongue
- English
- Weight
- 361 KB
- Volume
- 25
- Category
- Article
- ISSN
- 1573-9171
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📜 SIMILAR VOLUMES
## Abstract α‐(Phenyltelluro)esters **2** reacted with electron‐rich alkenes **3** in the presence of a catalytic amount of azobisisobutyronitrile (AIBN) as an initiator to give the corresponding addition products **4**. This carbotelluration of alkenes proceeded via a radical chain mechanism invol
Enantioselective conjugate addition reactions of alkyl radicals to a 0 -phenylsulfonyl enones are described. A bis-oxazoline-zinc triflate complex proved to be an effective catalyst leading to high enantioselectivities and chemical yields.