𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Radial functions of SiS X 1Σ from vibration-rotational spectra

✍ Scribed by J.F. Ogilvie


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
478 KB
Volume
183
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis


The radial functions for the potential energy and the adiabatic and nonadiibatic effects have been determined in the range 1.72<R/10-1" mG2.25 for the molecule SiS in the electronic ground state X 'Z directly from the published frequencies and wavenumbers of pure rotational and vibration-rotational transitions. Only twelve independent parameters were required to tit 3025 data whh an (unweighted) standard deviation 0.236 m-'.


📜 SIMILAR VOLUMES


Evaluation of adiabatic and nonadiabatic
✍ J.F. Ogilvie; J. Oddershede; S.P.A. Sauer 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 750 KB

We combined radial functions for the rotational g-factor and electric dipole moment, from molecular electronic computations but tested with experimental data, with spectral data of 557 pure rotational and vibration-rotational transitions of LiH in four isotopic variants; on this basis we evaluated s

Radial functions of the diatomic metal h
✍ J.F. Ogilvie 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 518 KB

The coefficients c j, 0 ~<j~< 6 or 8, defining the potential energy V(z) and coefficients of other radial functions related to adiabatic and nonadiabatic effects have been determined for the diatomic metal hydrides AgH, Gall, InH and TIH in their electronic ground states X ty. by a direct fit to the