Radial functions of the diatomic metal hydrides AgH, GaH, InH and TlH from vibration—rotational spectra
✍ Scribed by J.F. Ogilvie
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 518 KB
- Volume
- 191
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
The coefficients c j, 0 ~<j~< 6 or 8, defining the potential energy V(z) and coefficients of other radial functions related to adiabatic and nonadiabatic effects have been determined for the diatomic metal hydrides AgH, Gall, InH and TIH in their electronic ground states X ty. by a direct fit to the published wavenumbers of vibration-rotational transitions. The functions which are valid in specified ranges of internuclear distance depending on the molecule serve to reproduce the reported wavenumbers of the transitions within the uncertainty of the measurements. Comparisons are made with the fits of parameters reported by Urban, Birk, Polomsky and Jones.