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Racemization of amino acid derivatives. III. Rate of racemization and peptide bond formation of cysteine active esters

โœ Scribed by Kovacs, Joseph.; Mayers, George L.; Johnson, Robert Hall.; Cover, Richard E.; Ghatak, Usha R.


Book ID
118140915
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
927 KB
Volume
35
Category
Article
ISSN
0022-3263

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## Abstract A novel tool for polymerโ€assisted solution phase (PASP) esterification of amino acid and peptide derivatives has been developed. When treated with carboxylic acids, polymerโ€bound alkyltriazenes react with a loss of nitrogen and transfer of the alkyl moiety to the carboxylate anion to fo