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Peptide synthesis by a combination of solid-phase and solution methods III resin derivatives allowing minimum-racemization coupling of nα-protected amino acids

✍ Scribed by M Mergler; R Nyfeler; J Gosteli

Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
153 KB
Volume
30
Category
Article
ISSN
0040-4039

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📜 SIMILAR VOLUMES

Peptide synthesis by a combination of so
Peptide synthesis by a combination of solid-phase and solution methods IV minimum-racemization coupling of nα-9-fluorenylmethyloxycarbonyl amino acids to alkoxy benzyl alcohol type resins
✍ M. Mergler; R. Nyfeler; J. Gosteli; R. Tanner 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 175 KB

The cesium salts of N -9-fluorenylmethyloxycarbonyl (Fmoc) amino acids couple smoothly to new chloro derivatives of alkoxy benryl alcohol resins. While high loading is attained under mild reaction conditions racemization can be suppressed even with Cys and His derivatives.