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rac-(Z)-2-(1-Naphthylmethylene)-1-azabicyclo[2.2.2]octan-3-ol

✍ Scribed by Sonar, Vijayakumar N. ;Parkin, Sean ;Crooks, Peter A.


Book ID
118689990
Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
543 KB
Volume
63
Category
Article
ISSN
1600-5368

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rac-(Z)-2-(2,4-Dichlorobenzylidene)-1-az
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the oxygen atom labelled O16, while the minor component was placed in the most reasonable hydrogen bonding position, as dictated by the SHELXL (Sheldrick, 1997) commands "HFIX 147" and "HFIX 87" respectively.

(Z)-2-(2-Methoxy­benzyl­idene)-1-aza­bic
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The title compound, C 15 H 17 NO 2 , was prepared by basecatalyzed reaction of 2-methoxybenzaldehyde with 1-azabicyclo[2.2.2]octan-3-one. The configuration about the olefinic bond connecting the methoxyphenyl and 1-azabicylo[2.2.2]octan-3-one moieties is Z.