The title complex, [Ni(C~11~H~11~N~2~O~2~)~2~]~__n__~ or [Ni(D-trp)(L-trp)]~__n__~ [D-trp = (__R__)-2-amino-3-(3-indolyl)propionate and L-trp = (__S__)-2-amino-3-(3-indolyl)propionate], was formed by a hydrothermal method from hexaaquanickel(II) perchlorate and L-tryptophan. The Ni^II^ atom is locat
rac-Poly[bis(μ-tryptophanato)manganese(II)]
✍ Scribed by Xie, Yu ;Wu, Hao-Han ;Yong, Guo-Ping ;Wang, Zhi-Yong
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 290 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
A mixture of Mn(ClO 4 ) 2 (0.023 g, 0.15 mmol), l-tryptophan (0.060 g, 0.30 mmol), pyridine (0.10 ml), methanol (0.40 ml) and water
📜 SIMILAR VOLUMES
The centrosymmetric title compound, [Mn 2 (C 7 H 5 O 2 ) 4 -(C 5 H 5 N) 4 ], is a dinuclear manganese complex containing bridging and chelating benzoate ligands with trans pyridine ligands at each Mn centre.
The title complex, [Mn(C 2 O 4 )(C 3 H 7 NO) 2 ] n , forms extended one-dimensional chains with oxalate dianions bridging Mn II atoms in a bis-bidentate mode. The unique Mn II atom lies on a crystallographic twofold axis and is in a distorted octahedral coordination environment. There is a single we