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catena-Poly[[bis­(N,N-dimethyl­formamide)manganese(II)]-di-μ2-oxalato]

✍ Scribed by Chan, Ya-Nan ;Zhao, Hong-Kun ;Wang, Xiu-Guang ;Zhao, Xiao-Jun

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
223 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title complex, [Mn(C 2 O 4 )(C 3 H 7 NO) 2 ] n , forms extended one-dimensional chains with oxalate dianions bridging Mn II atoms in a bis-bidentate mode. The unique Mn II atom lies on a crystallographic twofold axis and is in a distorted octahedral coordination environment. There is a single weak intramolecular C-HÁ Á ÁO hydrogen-bond interaction [HÁ Á ÁO = 2.38 A ˚].

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