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Rac-(2R*,3R*)-S-Ethyl-4-Chloro-3-Hydroxy-2-Phenylbuthanethioate and Rac-(2R*,3R*)-S-Ethyl-2-Phenyl-3-(tosyloxy)buthanethioate: Dichotomy of the Stereoselectivity of the Mukaiyama Reaction

โœ Scribed by Oliver Vallat; Ana-Maria Buciumas; Reinhard Neier; Helen Stoeckli-Evans


Book ID
106404383
Publisher
Springer
Year
2009
Tongue
English
Weight
332 KB
Volume
40
Category
Article
ISSN
1572-8854

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Synthesis of (3R)-3-Hydroxy-2-Hexanone,
โœ Schrรถder, Frank ;Fettkรถther, Regina ;Noldt, Uwe ;Dettner, Konrad ;Kรถnig, Wilfrie ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 856 KB

## Abstract The following compounds were identified as male pheromone components of the longhorn beetles __Hylotrupes bajulus__ and __Pyrrhidium sanguineum__: (3__R__)โ€3โ€hydroxyโ€2โ€hexanone [(3__R__)โ€1], (2__S__,3__R__)โ€2,3โ€hexanediol [(2__S__,3__R__)โ€4] and (2__R__,3__R__)โ€2,3โ€hexanediol [(2__R__,3