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(R)-1-Phenyl­ethanaminium–(S,S)-2,3-dibromo­succinate–(R,R)-2,3-dibromo­succinic acid–water (2/1/1/2)

✍ Scribed by Fischer, Andreas

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
348 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

From an aqueous solution of racemic 2,3-dibromosuccinic acid and (R)-1-phenylethanamine, crystals of the title compound, C~8~H~12~N^+^·0.5C~4~H~2~Br~2~O~4~
^2−^·0.5C~4~H~4~Br~2~O~4~·H~2~O, were obtained in almost quantitative yield. The structure contains both enantiomers of the starting material, dibromosuccinic acid. The S,S enantiomer is present as a dianion and the R,R enantiomer as the neutral acid; both of these components lie on twofold rotation axes. The structure features a complex two-dimensional network of hydrogen bonds.

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