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Quinol Intermediates in the Oxidation of Phenols and Their Rearrangements 1

✍ Scribed by Goodwin, Sidney; Witkop, Bernhard

Book ID
126043015
Publisher
American Chemical Society
Year
1957
Tongue
English
Weight
897 KB
Volume
79
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Spiran isolation in the dienone-phenol r
Spiran isolation in the dienone-phenol rearrangement of steroidal p-quinols
✍ Antoni Planas; Jaime TomΓ‘s; Juan-Julio Bonet πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 French βš– 219 KB

The neutral form of the spirocation intermediate in the dienone-phenol rearrangement of a steroidal p-quinol has been isolated, providing a direct prove of the accepted mechanism. Changing acidic conditions, phenolic products were obtained.