✦ LIBER ✦

Quenching the Hysteresis in Single Crystals of a 1D Chain Iron(II) Spin Crossover Complex

✍ Scribed by Birgit Weber; Eike S. Kaps; Cédric Desplanches; Jean-François Létard

Publisher: John Wiley and Sons
Year: 2008
Tongue: English
Weight: 287 KB
Volume: 2008
Category: Article
ISSN: 1434-1948
DOI: 10.1002/ejic.200800391

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The unusual grinding effects observed in the 1D spin crossover polymer [FeL(bipy)]~n~ (1), with L being a tetradentate N~2~O~2~^2–^ coordinating Schiff base type ligand {(3,3′)‐[1,2‐phenylenebis(iminomethylidyne)]bis(2,4‐pentanedionato)(2–)‐N,N′,O^2^,O^2^′} and bipy = 4,4′‐bipyridine, are investigated using magnetic measurements, X‐ray powder diffraction and optical reflectivity studies. The observed behaviour can be explained when solvent effects are taken into account. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

📜 SIMILAR VOLUMES

Spin-Crossover Studies on a Series of 1D

Spin-Crossover Studies on a Series of 1D Chain and Dinuclear Iron(II) Triazine-Dipyridylamine Compounds

✍ Suzanne M. Neville; Ben A. Leita; Daniel A. Offermann; Martin B. Duriska; Boujem 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 333 KB

Spin-Crossover Studies on a Series of 1D

Spin-Crossover Studies on a Series of 1D Chain and Dinuclear Iron(II) Triazine-Dipyridylamine Compounds (Eur. J. Inorg. Chem. 8/2007)

✍ Suzanne M. Neville; Ben A. Leita; Daniel A. Offermann; Martin B. Duriska; Boujem 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 110 KB

Spin Crossover in a Family of Iron(II) C

Spin Crossover in a Family of Iron(II) Complexes with Hexadentate ligands: Ligand Strain as a Factor Determining the Transition Temperature

✍ Galina S. Matouzenko; Serguei A. Borshch; Erwann Jeanneau; Mark B. Bushuev 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 460 KB 👁 2 views

## Abstract This paper reports the synthesis of a family of mononuclear complexes [Fe(L)]X~2~ (X=BF~4~, PF~6~, ClO~4~) with hexadentate ligands L=Hpy‐DAPP ({bis[__N__‐(2‐pyridylmethyl)‐3‐aminopropyl](2‐pyridylmethyl)amine}), Hpy‐EPPA ({[__N__‐(2‐pyridylmethyl)‐3‐aminopropyl][__N__‐(2‐pyridylmethyl)

The Nature of Spin Crossover and Coordin

The Nature of Spin Crossover and Coordination Core Distortion in a Family of Binuclear Iron(II) Complexes with Bipyridyl-Like Bridging Ligands

✍ Galina S. Matouzenko; Erwann Jeanneau; Alexander Yu. Verat; Yannick de Gaetano 📂 Article 📅 2012 🏛 John Wiley and Sons 🌐 English ⚖ 461 KB