The ralc conskmts of quenching of singlet :mtl triplet states by oxygen hnve been measured for nine :~rom:~~ic h.vdroc:Irbons in solution. Singlcl quenching is diffusion controlled and similnr in nil cases but triplet quenching is slo~cr :md the quenching rrltc constant is closely r&ted to the recip
Quenching of excited singlet and triplet states of aromatic hydrocarbons by oxygen and nitric oxide
โ Scribed by J.B. Birks
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- English
- Weight
- 509 KB
- Volume
- 1-2
- Category
- Article
- ISSN
- 0022-2313
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๐ SIMILAR VOLUMES
Quenching of aromatic excited singlet states (9,10-dimethyl anthracene, 9,10-diphenyl anthracene and perylene) by nitroxyl radical was studied by flash photolysis and fluorimetrically. It is established that the dominant quenching mechanism is enhanced intersystem crossing in the collision complex w
The mechanism of fluorescence quenching of anthracene by dimethylmercury, tetramethyllead end tetramethyltin has been examined by fluorescence and flash photolysis measurements. The increased rates OF SI -T, and TI -S6 Intersystem-crossings induced by the heavy-atom molecules are discussed
Evidence rs presented that the excited singlet and triplet states of aromatic hydrocarbons are oxidised by methyi viologen (hlV2>. Rate constants for electron transfer from triplet naphthalene, anthracene, phenanthrene and fluoranthene are close to diffusion-controlled whereas those for triplet l-cy