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Quenching of C2(a 3Πu) produced in an intense infrared laser field

✍ Scribed by S.V. Filseth; G. Hancock; J. Fournier; K. Meier

Publisher: Elsevier Science
Year: 1979
Tongue: English
Weight: 487 KB
Volume: 61
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(79)80646-6

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✦ Synopsis

Cz(a 3Ru) has bern

produced in the multiplephoton dissociation oi'acryionitrile, C2H$N, by a TEA CO= laser. Laserinduced fiuorescence has been used to determine time-resolved reI&ve Cz concentrations in the presence of added AI and 02 and second-order rate constants of 2 X IO-r5 and 3.4 X 10-r* cm3 molecule-' s-l have been obtained for these two quenchers, respectively. Vacuum-ultraviolet chemiluminescence is observed in the quenching by 02_

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