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Quenching and radiative lifetimes for NH(b1Σ+, υ′ = 0)

✍ Scribed by B. Gelernt; S.V. Filseth; Tucker Carrington

Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
381 KB
Volume
36
Category
Article
ISSN
0009-2614

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✦ Synopsis

ElectroniulIy excited NIf(b ' C' , u' = Cl) has heen produced in the vacuum ultraviolet photolysis of ammonia at pressures in the millitosr range. Absolute rate coefficients for quenching and radiation have been determined by time-resolved measurements of the emission near 471 nm of the 0,O band of the NH(b'C+-X3T) system. A radiative Lifetime of 17.8-f;: ms is reported snd rate coefficients are reported for quenching by Ar, NH3, CH4, CO and 02. None of these collision partners leads to rapid quenching.

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