Quasiclassical dynamics of a wavepacket prepared by the resonant excitation of a diatomic molecule
โ Scribed by I.M. Umanskii; S.I. Vetchinkin; V.V. Eryomin
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 438 KB
- Volume
- 208
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
The quasiclassical analysis of the one-dimensional finite and infinite motion of spectrally narrow wavepackets is presented. It is shown that the wavepacket dynamics depends crucially on the type of excitation, below or above the classical transition point.
The advantages of the temporal representation of the packet (Y(x, t) at x=const.) over the coordinate representation ( p(x, t) at t=const.) are discussed.
๐ SIMILAR VOLUMES
Exact quantum-mechanical calculations of the dissociation dynamics of Nat excited by a femtosecond pulse are carried out using an iteration scheme for computing the wavepacket dynamics in multiphoton processes. The results show that nonadiabatitally ramified packets interfere with each other at the
The coupled equatiops of molecular collision theory can be formulated in such a way as to yield the amp!itude for resommce Roman scattering of li&t by ;L diatomic molecule. Tao vxknts of tke method can be adopted, characterized by different choices for the potential matrices. \_%li molecular potenti