Quasi-one-dimensional bis(ethylenedithio)tetrathiafulvalene charge- transfer salts with paramagnetic Group 6 anions
โ Scribed by Kepert, Cameron J.; Kurmoo, Mohamedally; Truter, Mary R.; Day, Peter
- Book ID
- 121459857
- Publisher
- The Royal Society of Chemistry
- Year
- 1997
- Tongue
- English
- Weight
- 500 KB
- Volume
- 4
- Category
- Article
- ISSN
- 1472-7773
- DOI
- 10.1039/A606025K
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The electrochemical combination of the paramagnetic anion [Cr(NCS) 6 ] 3-with the organic p-donors bis(ethylenedithio)tetrathiafulvalene (ET) and 4,5-bis(2-hydroxyethylthio)-4',5'-ethylenedithiotetrathiafulvalene (DHET-EDTTTF) leads to two new radical cation salts, namely (ET) 4 [Cr(NCS) 6 ]โขPhCN (1
Two new charge transfer salts of BEDT-TTF, bis (ethylenedithio) tetrathiafulvalene, with thiocyanato-metal complex anions have been synthesized and characterized as (BEDT-TTF) 4 [Fe(NCS) 6 ] ' CH 2 Cl 2 and (BEDT-TTF) 2 [Cr(NCS) 4 (bipym)] ' 0.15H 2 O, where bipym โซุโฌ 2,2-bipyrimidine. The Fe salt,
The preparation, X-ray structures and magnetic properties of two isostructural new charge transfer salts: (BO)[M (isoq) 2 (NCS) 4 ]; M=Cr III (1), Fe III (2) and isoq=isoquinoline are reported. Their structure consists of alternate organic and inorganic layers, each layer being formed by mixed colum