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Molecular Charge-Transfer Salt of BEDT−TTF [Bis(ethylenedithio)tetrathiafulvalene] with the Oxalate-Bridged Dimeric Anion [Fe 2 (C 2 O 4 ) 5 ] 4-

✍ Scribed by Rashid, Samina; Turner, Scott S.; Day, Peter; Light, Mark E.; Hursthouse, Michael B.


Book ID
126406086
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
53 KB
Volume
39
Category
Article
ISSN
0020-1669

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New Molecular Charge Transfer Salts of B
✍ Scott S. Turner; Peter Day; Thomas Gelbrich; Michael B. Hursthouse 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 341 KB

Two new charge transfer salts of BEDT-TTF, bis (ethylenedithio) tetrathiafulvalene, with thiocyanato-metal complex anions have been synthesized and characterized as (BEDT-TTF) 4 [Fe(NCS) 6 ] ' CH 2 Cl 2 and (BEDT-TTF) 2 [Cr(NCS) 4 (bipym)] ' 0.15H 2 O, where bipym ‫؍‬ 2,2-bipyrimidine. The Fe salt,