✦ LIBER ✦

Quantum Treatment of Intermolecular Multiple-Quantum Coherences with IntramolecularJCoupling in Solution NMR

✍ Scribed by Sangdoo Ahn; Warren S. Warren; Sanghyuk Lee

Publisher: Elsevier Science
Year: 1997
Tongue: English
Weight: 340 KB
Volume: 128
Category: Article
ISSN: 1090-7807
DOI: 10.1006/jmre.1997.1226

No coin nor oath required. For personal study only.

✦ Synopsis

A recently introduced density matrix picture for dipolar effects

Alternatively, it is possible to write a density matrix treatin solution NMR (1996, J. Chem. Phys. 105, 874) gave complete ment which explicitly shows the origin of the cross peaks solutions for intermolecular multiple-quantum coherences for sinin intermolecular multiple-quantum coherences (iMQCs). gle-component samples without scalar couplings. This paper, for This ''quantum picture' ' (3, 11) discards two main assumpthe first time, shows that this quantum picture can lead to explicit tions of NMR theory-the high-temperature approximation signal expressions for multicomponent samples of molecules with and the neglect of intermolecular dipole-dipole interactions.

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