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Detection of Intermolecular Heteronuclear Multiple-Quantum Coherences in Solution NMR

✍ Scribed by Patricia R. Bachiller; Sangdoo Ahn; Warren S. Warren

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
139 KB
Volume
122
Category
Article
ISSN
1064-1858

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✦ Synopsis

assuming that the sample begins at equilibrium. I and S are Over the past few years, we and others have shown that, the two different kinds of spins ( 1 H and 13 C in our experiin a wide variety of two-dimensional solution NMR experiments, respectively), and the indices i and j run up to the ments, samples with at least one concentrated component number of I and S spins in the sample. Note that (such as proteins in water) can grossly violate the predictions of conventional theory (1-16). They show cross peaks in the indirectly detected dimension with all of the experi-

COMMUNICATIONS Farmer II, Experimental NMR Conference, Boston, Massachusetts, do solvent-solvent peaks; for example, the zero-quantum

March 1995.

solvent-solute signal (r Γ… 0, k Γ… 1) does not vanish,

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