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Quantum mechanical treatment of the collinear H+ + H2 system. The uncoupled system

✍ Scribed by Z.H. Top; M. Baer

Publisher: Elsevier Science
Year: 1974
Tongue: English
Weight: 605 KB
Volume: 28
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(74)80364-7

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✦ Synopsis

A fully converged close coupling study is performed of the collinear (I?+ Hz) system on the lowest potential energy surkce.

The surface is derived by the DiMZO (diatomic in molecules-zero overlap) method. Transition probabilities for the reactions: I$ + Hz iv'= 0; 1) + H:! (v') + H+; Y' '= 0,. . ., 7 are given for a number of total energies in the range from 1 eV to 3 eV. It is found that for this energy region the transition v = 0 -v' = 0 is the most preferential. This fact leads us to believe that addition of the upper surface will hove a minor effect on the calculated probabilities of transitions from v = 0 in the above-mentioned en&y range.

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