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Quantum dynamics of the collinear CsHH system

✍ Scribed by B. Lepetit; M. Le Dourneuf; J.M. Launay; F.X. Gadéa

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
441 KB
Volume
135
Category
Article
ISSN
0009-2614

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✦ Synopsis

Qu~tum-m~b~ica1

transition probabilities for the colhnear reaction Cs(~~)~HH(~) -4 CsH(v')+H have been computed using hyperspherical coordinates. The reaction involves a strong non-localized iomc-covafent electronic coupling. Large probabilities, with sharp resonance features, are obtained for nearly thermoneutrai transitions such as Cs(6s) +HH(u=6), Cs(7p)+HH(u=O)-+ CsH(v'=O)+H.

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