The quantum-mechanical equivalent of a classically vibrating molecular ion during an ion-pair formation collision is prcsenrcd. The classical vibration in the quanta1 representation is explained as an interference between partial waves which ~oI\c along neighbowing vibronic states during the collisi
Quantum mechanical reaction dynamics in collisions of chlorine atom with hydrogen molecule
β Scribed by Meishan Zhao
- Book ID
- 112060234
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 513 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0256-7660
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Differential reaction cross sections have been masured as a function of inithl trantitional enegy for the 1 afom abstraction reactions of Cl atoms with CII,l. CZHsI, C,H,I molecules. At lower initial transhtiorul energy. long-lived collision dynamics are observed which persist at hgher initial trans
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