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Quantum mechanical and NMR spectroscopy studies on the conformations of the hydroxymethyl and methoxymethyl groups in aldohexosides

✍ Scribed by Igor Tvaroška; François R. Taravel; Jean Pierre Utille; Jeremy P. Carver


Book ID
108309323
Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
198 KB
Volume
337
Category
Article
ISSN
0008-6215

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NMR and molecular mechanics studies on t
✍ Robert Glaser 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 484 KB

## Abstract The NMR parameters of (−)‐scopolamine free base in CDCl~3~ determined by Sarazin __et al.__ were used to reevaluate some of the stereochemical conclusions recently reported by the authors. Similarly to the case with the protonated salt, the major contributor to the fast exchange limit t