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Quantum-Chemical Study of the Conformational Composition of 2,2,4,5-Tetramethyl-1,3-dioxa-2-silacyclohexane Stereoisomers

โœ Scribed by V. V. Kuznetsov; S. A. Bochkor

Book ID
110291848
Publisher
SP MAIK Nauka/Interperiodica
Year
2001
Tongue
English
Weight
130 KB
Volume
42
Category
Article
ISSN
0022-4766

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Reaction of 2,2,4,5-Tetramethyl-1,3-dioxa-2-silacyclohexane with Diisobutyl Ester of Isobutylboronic Acid. -The trifluoroboranecatalyzed reaction of the title 1,3,2-dioxasilacyclohexane (I) with diisobutyl isobutylborate (II) results in a recyclization to afford the 1,3,2dioxaboracyclohexane (III).