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ChemInform Abstract: Reaction of 2,2,4,5-Tetramethyl-1,3-dioxa-2-silacyclohexane with Diisobutyl Ester of Isobutylboronic Acid.

✍ Scribed by V. V. KUZNETSOV


Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis


Reaction of 2,2,4,5-Tetramethyl-1,3-dioxa-2-silacyclohexane with Diisobutyl Ester of Isobutylboronic Acid.

-The trifluoroboranecatalyzed reaction of the title 1,3,2-dioxasilacyclohexane (I) with diisobutyl isobutylborate (II) results in a recyclization to afford the 1,3,2dioxaboracyclohexane (III). The reaction proceeds with retention of the initial cis/trans ratio. -(


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