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Quantum chemical studies of a model for peptide bond formation: formation of formamide and water from ammonia and formic acid

โœ Scribed by Oie, Tetsuro; Loew, Gilda H.; Burt, Stanley K.; Binkley, J. Stephen; MacElroy, Robert D.

Book ID
126915897
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
730 KB
Volume
104
Category
Article
ISSN
0002-7863

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Ab initio study of catalyzed and uncatal
Ab initio study of catalyzed and uncatalyzed amide bond formation as a model for peptide bond formation: Ammonia-Glycine reactions
โœ Tetsuro Oie; Gilda H. Loew; Stanley K. Burt; Robert D. Macelroy ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 1006 KB

As a model reaction for peptide and bond formation, the s N 2 reactions between glycine and ammonia have been studied with and without amine catalysis: using ab initio molecular-orbital methods. For each of the catalyzed and uncatalyzed reactions, two reaction mechanisms have been examined: a two-s