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Quantum chemical investigation of the reaction of phosphine with alcohol in the coordination sphere of platinum(IV) and platinum(II)

✍ Scribed by Ya. A. Dorfman; L. V. Levina; D. M. Doroshkevich


Book ID
112365691
Publisher
Springer
Year
1993
Tongue
English
Weight
538 KB
Volume
28
Category
Article
ISSN
0040-5760

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The electrochemical reduction and DNA binding have been studied for a series of platinum(IV) complexes with Cl-, OH-, and carboxylate anions as the axial ligands ; [Pt(en)Cl4], [Pt(en)Cl2(OH)2], and [Pt(en)Cl2(OC(O)R)2], R = CH3, CH2CH3, CH2CH2CH3. Cathodic reduction potentials vary by more than 650