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Role of the ligands in affecting the stoichiometry and the rate of reactions between platinum(IV) and platinum(II) complexes

✍ Scribed by Arnaldo Peloso


Book ID
108429040
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
968 KB
Volume
10
Category
Article
ISSN
0277-5387

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The Influence of the Axial Ligands of a
✍ Ellis, LT; Er, HM; Hambley, TW πŸ“‚ Article πŸ“… 1995 πŸ› Commonwealth Scientific and Industrial Research Or 🌐 English βš– 612 KB

The electrochemical reduction and DNA binding have been studied for a series of platinum(IV) complexes with Cl-, OH-, and carboxylate anions as the axial ligands ; [Pt(en)Cl4], [Pt(en)Cl2(OH)2], and [Pt(en)Cl2(OC(O)R)2], R = CH3, CH2CH3, CH2CH2CH3. Cathodic reduction potentials vary by more than 650