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Quantum chemical calculations on the structure and conformation of substituted ethylene radical cations and on their ESR spectra

โœ Scribed by Josef Kalcher; G. Olbrich


Book ID
119115995
Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
780 KB
Volume
104
Category
Article
ISSN
0166-1280

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Zinc(II) complexes of substituted tetraphenylporphyrins, Zn[T(X-P)P], where X = H, p-F, p-Cl, m-Cl, p-CH 3 O, and m-CH 3 O, have been synthesized and characterized. Peripheral substitution shows marked changes in the chemical shifts of the phenyl proton resonances and E 1/2 values of the redox coupl