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Quantum Chemical and Statistical Rate Study of the Reaction of O( 3 P) with Allene: O-Addition and H-Abstraction Channels

โœ Scribed by Nguyen, Thanh Lam; Peeters, Jozef; Vereecken, Luc

Book ID
126202493
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
500 KB
Volume
110
Category
Article
ISSN
1089-5639

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The dynamics of reactions of O(3P) atoms
The dynamics of reactions of O(3P) atoms with allene and methylacetylene
โœ M.C. Lin; R.G. Shortridge; M.E. Umstead ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 552 KB

The reactions of O(3P) atoms with allene and mcthylacetylcne: 0 + CH2=C=CHL 5 CO +C2HG, a@ = -119.4 kcal/mole, 0 + CH3-GCH 2 CO + C,E&,, 44 = -1!7.8 kcd/mole were studied at 293 K with a CO kser resonant absorption and ZI dischzqe-flow CC-sampling method. The CO formed in rcacrion (1) wax ibund to h