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Quantum Chemical and Kinetic Study of Formation of 2-Chlorophenoxy Radical from 2-Chlorophenol: Unimolecular Decomposition and Bimolecular Reactions with H, OH, Cl, and O 2

✍ Scribed by Altarawneh, Mohammednoor; Dlugogorski, Bogdan Z.; Kennedy, Eric M.; Mackie, John C.


Book ID
126424172
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
476 KB
Volume
112
Category
Article
ISSN
1089-5639

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The reactions of C1 and Br atoms with HzOz have been studied in the range of 300-350 K using the very-low-pressure-reactor technique. It was found that metathesis to produce HX and H02 is the only significant process (199%). For the reaction of Br 2 Br + HzO2 + HBr + HOz k z (300 K) = 1.3 f 0.45 X a