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Quantitative Study of Methyl Methacrylate-Poly(Ethylene Glycol) Methacrylate Copolymer Films using High Mass Resolution ToF-SIMS

✍ Scribed by Briggs, D.; Davies, M. C.

Publisher: John Wiley and Sons
Year: 1997
Tongue: English
Weight: 486 KB
Volume: 25
Category: Article
ISSN: 0142-2421
DOI: 10.1002/(sici)1096-9918(199708)25:9<725::aid-sia293>3.0.co;2-9

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✦ Synopsis

A previous XPS and low mass resolution (quadrupole) SIMS study of methyl methacrylate-poly(ethylene glycol) methacrylate random copolymers indicated (by XPS) a surface composition close to that of the bulk, however the trends in SIMS intensity ratios for peaks chosen to represent the individual monomers showed departures from linearity that were not understood. High mass resolution time-of-Ñight (ToF) SIMS data has shed light on the earlier results and, as a result, linear correlations have been established. In addition it has been possible to study high mass fragments derived from the poly(ethylene glycol) side chain.

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