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Quantitative structure–reactivity modeling of copper-catalyzed atom transfer radical polymerization

✍ Scribed by di Lena, Fabio; Chai, Christina L. L.

Book ID
120026222
Publisher
The Royal Society of Chemistry
Year
2010
Tongue
English
Weight
392 KB
Volume
1
Category
Article
ISSN
1759-9954

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The atom transfer radical polymerization (ATRP) of styrene has been studied using complexes of copper carboxylates. Compared with systems employing copper halides as the catalyst, the use of copper carboxylates resulted in faster polymerization rates and higher polydispersities. A ligand (dNbpy) to