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Controlled/“Living” Radical Polymerization. Atom Transfer Radical Polymerization Catalyzed by Copper(I) and Picolylamine Complexes

✍ Scribed by Xia, Jianhui; Matyjaszewski, Krzysztof

Book ID
118208893
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
125 KB
Volume
32
Category
Article
ISSN
0024-9297

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The atom transfer radical polymerization (ATRP) of styrene has been studied using complexes of copper carboxylates. Compared with systems employing copper halides as the catalyst, the use of copper carboxylates resulted in faster polymerization rates and higher polydispersities. A ligand (dNbpy) to