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Quantitative spectroscopic studies with the shock tube

โœ Scribed by Walter H. Wurster


Publisher
Elsevier Science
Year
1963
Tongue
English
Weight
668 KB
Volume
3
Category
Article
ISSN
0022-4073

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## Abstract The reactions of dimethyl ether (CH~3~OCH~3~, DME) with O(^3^P) and H atoms have been studied at high temperatures by using a shock tube apparatus coupled with atomic resonance absorption spectroscopy (ARAS). The rate coefficients for the reactions CH~3~OCH~3~ + O(^3^P) โ†’ CH~3~OCH~2~ +

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The rate coefficient for the reaction of the hydroxyl radical, OH, with propane has been measured at 1220 K in shock tube experiments, and a value of (1.58 ? 0.24) x l O I 3 cm3/mol s was obtained. This measured value is compared with previous experimental results and a transition-state theory calcu