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Quantitative Aspects of the Stereoselectivity in the Stereoregulated Polymerization of Racemic α-Olefins by Ziegler-Natta Catalysts

✍ Scribed by Montagnoli, Giorgio; Pini, Dario; Lucherini, Antonio; Ciardelli, Francesco; Pino, Piero

Book ID
127142301
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
336 KB
Volume
2
Category
Article
ISSN
0024-9297

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Competing side reactions in the polymeri
Competing side reactions in the polymerization of α-olefins by ziegler-natta catalysts
✍ Ketley, A. D. ;Moyer, J. D. 📂 Article 📅 1963 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 490 KB

## Abstract The polymerization of 3‐methylbutene‐1 by TiCl~3~–Al(C~2~H~5~)~3~ catalysts in dilute solution above 80°C. yields a polymer which is contaminated with polyethylene. By using tagged aluminum alkyl, this polyethylene was shown to arise almost wholly by displacement of ethylene from the al