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Chiral discrimination in the polymerization of α-olefins by Ziegler-Natta initiator systems

✍ Scribed by Francesco Ciardelli; Angelina Altomare; Carlo Carlini

Book ID
113215220
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
960 KB
Volume
16
Category
Article
ISSN
0079-6700

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📜 SIMILAR VOLUMES

Competing side reactions in the polymeri
Competing side reactions in the polymerization of α-olefins by ziegler-natta catalysts
✍ Ketley, A. D. ;Moyer, J. D. 📂 Article 📅 1963 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 490 KB

## Abstract The polymerization of 3‐methylbutene‐1 by TiCl~3~–Al(C~2~H~5~)~3~ catalysts in dilute solution above 80°C. yields a polymer which is contaminated with polyethylene. By using tagged aluminum alkyl, this polyethylene was shown to arise almost wholly by displacement of ethylene from the al