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Quantitative anionic synthesis of pyrene-end-labeled polystyrene and polybutadiene

✍ Scribed by Quirk, Roderic P.; Schock, Laurel E.


Book ID
118007918
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
617 KB
Volume
24
Category
Article
ISSN
0024-9297

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Both polystyrenes and polyisoprenes with 1,3-butadienyl end-groups were synthesized by the reactions of polystyryl and polyisoprenyl anions with 6-bromo-3-methylene-1 -hexene (3). The 1,3-butadienyl end-group was further transformed to an anhydride function by Diels-Alder reaction with maleic anhydr