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Quantitative analysis and determination of the enantiomeric purity of glycerides by 13C NMR spectroscopy. Application to the lipase-catalysed transesterification of triacylglycerides

✍ Scribed by Claude Rabiller; Françoise Maze

Publisher: John Wiley and Sons
Year: 1989
Tongue: English
Weight: 299 KB
Volume: 27
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1260270611

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✦ Synopsis

13C NMR spectroscopy can be used for the quantitative analysis of mixtures of glycerides and the enantiomeric purity can be determined by using Eu(hfbc),-d reagent. This technique was applied to the study of the reaction mixture obtained from the transesterification of tributyrin catalysed by My-lipase (Can&& cylindracea). A 'preference' of this lipase for the pro-R ester function of tributyrin is demonstrated.

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