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Quantitation of chemical exchange rates using pulsed-field-gradient diffusion measurements

โœ Scribed by Michael Andrec; James H. Prestegard

Book ID
110373726
Publisher
Springer Netherlands
Year
1997
Tongue
English
Weight
346 KB
Volume
9
Category
Article
ISSN
0925-2738

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Pulsed-field-gradient NMR techniques are demonstrated for measurements of time-dependent gas diffusion. The standard PGSE technique and variants, applied to a free gas mixture of thermally polarized xenon and O2, are found to provide a reproducible measure of the xenon diffusion coefficient (5.71 x