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Quantification of 13C in solids using CPMAS-DD-NMR spectroscopy

✍ Scribed by David G. Rethwisch; Mary A. Jacintha; Cecil R. Dybowski

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 985 KB
Volume: 283
Category: Article
ISSN: 0003-2670
DOI: 10.1016/0003-2670(93)80264-l

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✦ Synopsis

Quantitative analysis of several standard materials is used to evaluate various techniques for analysis of 13C cross polarization magic angle spinning dipolar decoupling (CPMAS-DD)_NMR spectra. These results suggest that uncertainty in the kinetics of the initial cross-polarization process may lead to systematic errors in the fitting of CPMAS-DD-NMR data. Methods are suggested to minimize the effects of this potential source. of error. These results indicate that "C CPMAS-DD-NMR can give quantitatively reliable results.

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