Quadrupole moment of vanadium-51: forbidden lines in EPR of oxovanadium(IV)

✍ Scribed by R.L. Belford; D.T. Huang; H. So

• Book ID: 103010323
• Publisher: Elsevier Science
• Year: 1972
• Tongue: English
• Weight: 324 KB
• Volume: 14
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(72)87214-2

✦ Synopsis

The first mcusuremcnts of sign and magnitude ofquadrupole couplin, 0 in tetravalent vanadium XC obtained from forbidden EPR lines in crystals. For VO" in Pd(C6IiSCOCHCOCH,)-, ctqQ = -24 ? 16 1IH.z: for VW50~~ in Na2(CH3NH3)2V2\',0 19.6H20. czqQ = -8 2 I Mi-k These values support 2 = -0.10 2 0.06 b for jlV. The quadrupolc rnorncnt (Q) of the 51V isotope