✦ LIBER ✦

Quadrupole moment of vanadium-51: forbidden lines in EPR of oxovanadaium(IV): Chem. Phys. Letters 14 (1972) 592.

Book ID: 103012615
Publisher: Elsevier Science
Year: 1972
Tongue: English
Weight: 46 KB
Volume: 15
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(72)80218-5

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✦ Synopsis

The tungstovanadate samples were prepared, characterized, and kindly provided by Drs. C.M. Flynn and M.T. Pope, Georgetown University, to be published. 464.

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Quadrupole moment of vanadium-51: forbid

Quadrupole moment of vanadium-51: forbidden lines in EPR of oxovanadium(IV)

✍ R.L. Belford; D.T. Huang; H. So 📂 Article 📅 1972 🏛 Elsevier Science 🌐 English ⚖ 324 KB

The first mcusuremcnts of sign and magnitude ofquadrupole couplin, 0 in tetravalent vanadium XC obtained from forbidden EPR lines in crystals. For VO" in Pd(C6IiSCOCHCOCH,)-, ctqQ = -24 ? 16 1IH.z: for VW50~~ in Na2(CH3NH3)2V2\\',0 19.6H20. czqQ = -8 2 I Mi-k These values support 2 = -0.10 2 0.06 b