✍ Scribed by Scott Gronert
No coin nor oath required. For personal study only.
| I. | Introduction | 000 |
| II. | General Features of Ion Traps | 000 |
| | A. Dynamic Range in Kinetics Measurements | 000 |
| | B. Temperature | 000 |
| | C. Trapping Windows | 000 |
| | D. MS^n^ | 000 |
| | E. Reagent Gas Introduction | 000 |
| III. | Mechanistic Studies of Organic Systems | 000 |
| | A. Substitutions and Eliminations | 000 |
| | B. Carbonyl Addition Reactions | 000 |
| | C. Electrophilic Reaction Processes | 000 |
| | D. Chemical Ionization and Related Work | 000 |
| | E. Organometallic and Related Systems | 000 |
| | F. Miscellaneous Reactions | 000 |
| IV. | Concluding Remarks | 000 |
| References | 000 |
Over the past several decades, quadrupole ion traps have become important instruments in the study of gas phase ion/molecule reactions. As a part of this work, they have been employed in a number of studies focused on fundamental organic reaction mechanisms. In this review, the general features and limitations of quadrupole ion traps are discussed followed by a description of representative ion trap studies of organic reaction mechanisms such as substitution, elimination, and acyl transfer reactions. © 2004 Wiley Periodicals, Inc.
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