It is demonstrated that the wealth of information about damped quantum rotation of CD 3 groups, contained in quadrupolar echo spectra, can be fully explored in a broad temperature range using a method of iterative analysis of the spectral lineshapes. The recently reported lineshape equation which, a
Quadrupolar Echo Spectra of the Tunneling CD3Group
β Scribed by Z. Olejniczak; A. Detken; B. Manz; U. Haeberlen
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 195 KB
- Volume
- 118
- Category
- Article
- ISSN
- 1064-1858
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The high-resolution infrared spectra of the lowest fundamental bands n 3 and n 6 of 12 CD 3 I and 13 CD 3 I have been measured using a Fourier transform spectrometer. The bands are analyzed on one hand by taking into account the Coriolis resonance n 3 /n 6 and on the other hand without this Coriolis
The crystal structure of \(\mathrm{Cs}_{7} \mathrm{Cd}_{3} \mathrm{Br}_{13}\), recently described as noncentrosymmetric in space group \(/ \overrightarrow{4} c 2\), should instead be described as centrosymmetric, space group \(14 / \mathrm{mcm}\). Other details of the structure are effectively uncha