QM/MM Study of the Role of the Solvent in the Formation of the Charge Separated Excited State in 9,9‘-Bianthryl
✍ Scribed by Grozema, Ferdinand C.; Swart, Marcel; Zijlstra, Robert W. J.; Piet, Jacob J.; Siebbeles, Laurens D. A.; van Duijnen, Piet Th.
- Book ID
- 126126592
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 167 KB
- Volume
- 127
- Category
- Article
- ISSN
- 0002-7863
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📜 SIMILAR VOLUMES
The intramolecular electron-transfer state of 9.9'-bianthryl was investigated in viscous solvents at high pressures. In the low-pressure region, there is a true equilibrium between the electron transfer and locally excited states, whereas the increase in the viscosity of the solvents becomes the dom
The kinetics of formation of an excited charge-transfer (CT) state in ?-(9-antllrvl)\_N,h'-di~iet~~~laniline have been studied by means of steady-state and nanosecond time-resolved fh~orcsctnce. It is concluded rhat the escited CT state is formed irreversibly at room temperature in ethyl acetate on